| Quiz 13; Problems 3, 4, 9, 10, 11, 12, 29, 30, 38, 39, 46, 47, 50, 51, 52 |
| TURN IN: 4, 10, 12, 30, 38, 46, |
| 4. Use TC = (5/9)(TF - 32) or TF = 9/5TC + 32 . Either way will get your answer in F. |
| 10. Use equation 13-1b. The steel rivet must
be cooled down in order to fit in the hole. That
way, when the temperature rises again, there will be a very
tight fit--- so tight that the structure will survive everyday
wear and tear, not to mention possible earth shaking. Thus equation
13-1b is with a negative change in temperature. Set up the following
equation: 1.869 = 1.871 + (1.871)·(alpha)·(change in temperature). Solve for the negative change in temperature. Then find the NEW temperature, given the initial temperature of 20 oC. |
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12. Equation 13-2. In the spirit of the previous problem, I want you to find the NEW volume after you find the CHANGE in volume using the initial given volume. To get the initial volume, use a general formula, which you can Google or look up in a book. (See example 13-11 for example) |
| 29. See example 13-13 and the equation directly
above it on page 366: P1V1/T1 = P2V2/T2 . Solve for the new volume V2 . The first volume is given. Note P1 = 1.00 atm and T1 = 273 K (under STP conditions explained on page 364), whereas P2 = 3.00 atm. Note: You must convert T2 = 38.0 oC to Kelvin . |
| 30. See the previous problem, example 13-13 and the equation directly
above it on page 366 for helpful methodology. P1V1/T1 = P2V2/T2 . IN THIS CASE, YOU WANT T2. Convert temperatures to K. V2 = (1/9) V1 . The first temperature is given. The first pressure = 1.0 atm, the second pressure = 40.0 atm . |
| 38. See the previous problem, example 13-13 and the equation directly
above it on page 366 for helpful methodology. But P1V1/T1 is NOT P2V2/T2 . Why? Because the numbers of moles is not constant. You have to use the ideal gas law which states that PV = nRT in a different way. We see that n = PV/(RT) = number of moles. Now write n1 = P1V1/RT1 and n2 = P2V2/RT2 . Subtract them to find the difference between the number of moles in the two cases: n1 - n2 = P1V1/RT1 - P2V2/RT2 . Then divide the difference by n1 to get the fractional change. Note that this difference is positive since you initially had more moles. Note that P1 = P2 . Convert temperatures to Kelvin K . |
| 46. (a) (3/2)kT is the average kinetic energy. See equation 13-8. (b) N(3/2)kT = n(3/2)RT, where n is the number of moles. Note that N is the number of particles; I did a conversion relating R to k. |